Cryogenics produces and studies materials in extremely cold temperatures. Ultra-cold temperatures change the chemical properties of materials. This has become an area of study for researchers who examine different materials as they transition from a gas to a liquid to a solid state. These studies have led to advances in not only our understanding of different materials but the creation of entirely new technologies and industries.
The temperature of any material is the measure of the energy that it contains. Rapidly moving molecules have a higher temperature than slower-moving molecules.
For example, while water transforms from a liquid to a solid at 32° F (0° C), cryogenic temperatures range much lower; from -150°C to -273° C. The temperature -273° C is the absolute lowest that can be achieved. At this temperature, the actions of all molecules stop, causing the molecules to be at the lowest possible state of energy.
Liquid gases at or below -150° C are also used to freeze other materials. Once a gas begins to liquefy, the environment is considered a cryogenic one. The most common gases that are turned into liquid for cryogenics are oxygen, nitrogen, hydrogen and helium.
History of Cryogenics
The word cryogenics comes from the Greek word “Kryos,” which means cold. This combined with the abbreviated English word “to generate” make the word we know as cryogenics.
Temperatures that are very cold are not measured in degrees Fahrenheit or Celsius but in Kelvins. Kelvins use the unit symbol K. It is named after Baron Kelvin who believed that at very low temperatures a new scale was needed that was not measured by the material state change of water like Fahrenheit or Celsius. Zero degrees Kelvin (0 K) is the theoretically coldest possible temperature.
In 1877 Rasul Pictet and Louis Cailletet liquefied oxygen for the first time, both using different methods for the process. Eventually, a third method of liquefying oxygen was discovered, and at this point in history oxygen was able to be liquefied at 90 K. Soon after, liquid nitrogen was achieved at 77 K. Scientists all over the world began competing to lower the temperature of matter to absolute zero.
The next breakthrough came in 1898 when James DeWar liquefied hydrogen at 20 K. This presented a new problem to researchers, as 20 K is also at a boiling temperature. However, this presented a further issue on how to handle and store gases at such temperatures. Hence the creation of DeWar flasks, which are used to store gases today.
The last major advance in the cryogenics industry came in 1908 when the physicist Heike Kamerling Onnes liquefied Helium at 4.2 K and then 3.2 K. The advances in cryogenics following this development have been much smaller because it is thermodynamic law that you can approach absolute zero, but never actually reach it. Technology has advanced much more since this last major discovery, and we can now freeze materials within very small distances from absolute zero, yet scientists still have not been able to break thermodynamic law where every particle has zero energy.
Cryogenic Tanks and Storage
Cryogenic tanks and storage solutions are essential components in industries requiring the storage and transportation of liquefied gases at extremely low temperatures.
These tanks are designed to safely hold gases like nitrogen, oxygen, and argon in their liquid state, maintaining temperatures as low as -196°C (-321°F). This construction of cryogenic tanks ensures minimal heat transfer, preserving the cryogenic liquids' low temperature and preventing vaporization. They are widely used in industries such as healthcare, food processing, and manufacturing, where the purity and stability of cryogenic gases are crucial.
One of the key benefits of cryogenic storage tanks is their ability to store large volumes of liquefied gases efficiently. These tanks are typically made from high-grade stainless steel or other materials that can withstand the extreme conditions required for cryogenic storage. With advanced insulation technology, cryogenic tanks reduce the risk of gas loss due to boil-off, making them a cost-effective solution for long-term storage.
What Is Cryogenics Used For?
Cryogenics is used in a variety of low-temperature physics research and applications. It can be used to produce cryogenic fields for rockets, in MRI machines that use liquid helium and require cryogenic cooling, storing large quantities of food, special effects fog, recycling, freezing blood and tissue samples, and even cooling superconductors.
Applications and uses:
Cryosurgery
Cryosurgery is a minimally invasive surgical technique that involves the use of extreme cold to destroy or remove abnormal tissues, such as tumors or warts. The procedure involves applying a freezing agent, such as liquid nitrogen or argon gas, directly onto the targeted area. This causes the tissue to freeze and ultimately die, allowing the body to naturally eliminate the damaged cells.
The science behind cryosurgery is based on the principle of controlled tissue destruction by rapid freezing and thawing. When the targeted tissue is exposed to extreme cold, the water inside the cells freezes and expands, causing the cell walls to rupture and the cells to die. The body's immune system then works to remove the dead tissue, leaving healthy tissue behind.
Cryosurgery has many advantages over traditional surgical techniques. It is a minimally invasive procedure that can be performed on an outpatient basis, reducing the need for hospitalization and recovery time. It also results in less scarring and pain compared to traditional surgery, and has a lower risk of infection and complications.
Cryosurgery is commonly used in dermatology to treat skin conditions such as warts, actinic keratosis, and skin cancers. It is also used in other medical specialties such as gynecology, urology, and gastroenterology to treat various conditions.
Cryoelectronic Cooling
Cryoelectronic cooling is an innovative technology that has revolutionized the field of superconductivity and spacecraft design. It involves the use of extreme cold temperatures to enable electrons in materials to move freely with little resistance. This technology has many advantages over traditional cooling methods, such as liquid cooling, because it is more efficient, reliable, and cost-effective.
In superconductivity research, cryogenic engineering plays a vital role in maintaining the low temperatures required for superconducting materials to operate at their full potential. These materials have the ability to conduct electricity with zero resistance when they are cooled to near absolute zero (-273.15°C). By using cryoelectronic cooling, scientists are able to achieve and maintain these extremely low temperatures, allowing for the creation of more efficient and powerful superconductors.
In addition to superconductivity research, cryoelectronic cooling is also used in spacecraft design. Spacecraft that travel through outer space are exposed to extreme temperatures, which can cause damage to their electronic systems. Cryoelectronic cooling provides a reliable and efficient way to maintain the temperature of electronic systems in spacecraft, ensuring that they operate at optimal performance levels.
One of the major advantages of cryoelectronic cooling is that it is a highly efficient method of cooling, requiring only a small amount of energy to maintain the required low temperatures. This makes it an ideal choice for space applications, where energy conservation is critical. Additionally, cryoelectronic cooling is a reliable and cost-effective method of cooling, with few moving parts and minimal maintenance requirements.
Cryobiology
Cryobiology is the study of the effects of low temperatures on organisms. There are six major areas of cryobiology:
- The study of cold-adaptation of microorganisms, plants, animals and vertebrates
- Cryopreservation of cell tissues and embryos used in invitro fertilization
- Preservation of organs
- Lyophilization, the freeze-drying of pharmaceuticals
- Cryosurgery
- Supercooling as applied to biological systems
Food Preservation
Cryogenics keeps foods fresh without chemical risk. It is an effective technique for food preservation that is used to maintain the quality and freshness of various food products.
Cryogenic preservation isn't just about cold - it freezes food products quickly so that it maintains its consistency, texture and taste. This makes cryogenic preservation an excellent option for high-value food items such as seafood, meat, and vegetables. This technique is particularly useful for maintaining the texture and quality of delicate food products that are easily damaged by other preservation methods such as heat treatment or dehydration.
Another benefit of cryogenic preservation is its ability to extend the shelf life of food products. By freezing food products at ultra-low temperatures, the growth of microorganisms that can cause spoilage and decay is inhibited, reducing the risk of foodborne illness and increasing the overall safety of the product.
To preserve packaged foods such as produce, the food items are typically sprayed with liquid nitrogen to absorb the heat within the produce. The nitrogen quickly evaporates before the food is packaged.
Transportation of Gases
Cryogenics is also used to transport gases that are not typically cryogenic. For example, using cryotechnology, gases can be transformed into liquids to make them easier to transport from one place to another. Take natural gas (LNG) which is a combination of ethane, methane and other gases. When these gases become liquefied, they take up far less space than if they remained gaseous. Therefore, transportation expenses become lower and the process becomes much easier.
Cryotherapy
Cryotherapy is a medical treatment that involves exposing the body to extremely cold temperatures. This can be achieved through various methods, including cryosaunas and cryospas, which allow individuals to stand in a chamber filled with cryogenic fluids for several minutes.
Proponents of cryotherapy claim that it offers numerous benefits to the body, including reducing inflammation, increasing energy, managing pain, and boosting metabolism. While research on cryotherapy is still relatively new, several studies have shown that it can be effective in reducing inflammation and pain in certain conditions, such as rheumatoid arthritis and fibromyalgia.
However, there are also potential risks associated with cryotherapy. Excessive exposure to cold temperatures can lead to hypothermia, which can be life-threatening. Additionally, cryotherapy can cause skin damage, particularly if the skin is wet or has open wounds.
Furthermore, while some individuals may experience immediate relief from pain and inflammation following cryotherapy, the long-term benefits of the treatment are still unclear. Some studies have suggested that cryotherapy may not be effective for all individuals and may even be harmful in some cases.
Cryonics
Cryonics is the process of cryo-preservation of humans or animals in the hope of reviving them at a later time when medical technology is advanced enough to cure the underlying cause of their death. Cryonics involves cooling the body to very low temperatures in a cryonic container filled with liquid nitrogen.
The cryopreservation process is performed immediately after death or sometimes even before if the individual is terminally ill and has chosen to undergo cryonic preservation. The goal of cryonics is to preserve the brain and other vital organs to enable future medical professionals to revive the person with their memories, consciousness, and personality intact.
While cryonics is a controversial topic, proponents argue that it offers hope for individuals who have been diagnosed with terminal illnesses or who may die from other causes. They argue that the advances in medical technology may one day make it possible to revive and cure the underlying cause of death, allowing individuals to continue living. Critics, however, argue that cryonics is a pseudoscience and that the chances of successfully reviving an individual are extremely slim. They also argue that the process of cryopreservation can cause significant damage to the body, and that it is unethical to offer false hope to individuals and their families.
What are the cryogenic fluids?
| Fluid | Boiling Point (K) | Boiling Point (°C) |
| Helium-3 | 3.19 | -269.96 |
| Helium-4 | 4.214 | -268.936 |
| Hydrogen | 20.27 | -252.88 |
| Neon | 27.09 | -246.06 |
| Nitrogen | 77.09 | -196.06 |
| Air | 78.8 | -194.35 |
| Fluorine | 85.24 | -187.91 |
| Argon | 87.24 | -185.91 |
| Oxygen | 90.18 | -182.97 |
| Methane | 111.7 | -161.45 |
Safety Measures in Cryogenic Systems and Storage
Safety measures in cryogenic systems and storage are critical due to the extreme temperatures and potential hazards associated with handling liquefied gases. Pressure relief valves are essential components, ensuring that the tanks do not exceed safe operating pressures, which could lead to dangerous explosions or leaks. Regular maintenance and inspection of these safety valves are crucial to ensure their proper functioning.
In addition to pressure control, gas detection safety monitoring and PPE is vital when handling cryogenic materials. Workers should use insulated gloves, face shields, and protective clothing to prevent frostbite and other injuries caused by direct contact with cryogenic liquids.
Proper training in the handling and storage of cryogenic gases is also necessary to prevent accidents and ensure that personnel are aware of the risks and safety protocols. Ventilation systems should be in place to manage the release of gases in the event of a leak, reducing the risk of asphyxiation in enclosed spaces. By adhering to these safety measures, industries can ensure the safe and efficient use of cryogenic systems.
CO2 Safety Systems in Cryogenic Applications
The importance of carbon dioxide (CO2) safety systems in cryogenic applications cannot be overstated, as CO2 poses significant risks when stored and handled at cryogenic temperatures. In its liquid state, CO2 is stored at extremely low temperatures and high pressures, which can lead to rapid vaporization if not properly managed.
This vaporization can result in a dangerous buildup of gas in confined spaces, leading to potential asphyxiation hazards. To mitigate these risks, CO2 safety systems are essential in monitoring and controlling CO2 levels, ensuring that the gas is safely vented or contained to prevent dangerous concentrations and overexposure.
By using an industrial fixed carbon dioxide gas detector, you can gain real-time, around-the-clock surveillance of CO2 concentrations and audible/visual indicators alarming personnel prior to a potential leak or hazard. These detectors with broader safety and control systems.
Fixed CO2 gas detectors can be connected to alarm systems, ventilation controls, and even automatic shutdown mechanisms, enabling rapid response to potential hazards.
These safety systems also enhance overall plant safety, reducing the risk of exposure to harmful CO2 levels for workers and minimizing the likelihood of costly operational disruptions. Additionally, fixed gas detectors are highly reliable and durable, designed to withstand harsh industrial environments, and a wide range of temperatures in cryogenics, which ensures long-term protection and reduces maintenance costs. Overall, the use of fixed CO2 gas detectors is a proactive measure that contributes to a safer and more efficient industrial operation.
Cryogenics: Challenges and Future Trends in the Industry
As technology rapidly evolves areas of cryogenics will continue to develop and eventually expand to more applications. While we can’t predict what developments will come next, what we do know is that safety around cryogenic fluids is a must, no matter which direction the research will progress.
One of the primary challenges for cryogenics in the future, is the high cost associated with the production, transportation, and storage of cryogenic materials. Maintaining extremely low temperatures requires sophisticated equipment and significant energy consumption, which can be expensive.
Additionally, the materials used in cryogenic systems must be highly durable and resistant to thermal stress, further driving up costs. Another challenge is ensuring the safety and reliability of cryogenic systems, as any failure in these systems can lead to serious accidents, product loss, and fatalities.
Looking ahead, the future of cryogenics is promising, with several emerging trends poised to address these challenges. Advances in insulation technology and materials science are expected to reduce costs and improve the efficiency of cryogenic systems. In addition, the growing interest in space exploration and quantum computing is also driving innovation in cryogenics, as these fields rely heavily on cryogenic technologies to achieve and maintain the ultra-low temperatures required for their operations.
Furthermore, the development of more compact and portable cryogenic systems is opening up new possibilities for their use in medical, scientific, and industrial applications. As the demand for cryogenics continues to grow, the industry is likely to see significant advancements that will enhance its capabilities and accessibility for all.
References
- https://academickids.com/encyclopedia/index.php/Cryogenics
- https://schoolworkhelper.net/cryogenics-history-overview/
- https://www.encyclopedia.com/science-and-technology/physics/physics/cryogenics
- https://www.azonano.com/article.aspx?ArticleID=5091
- https://science.jrank.org/pages/1893/Cryogenics.html
- https://www.thoughtco.com/cryogenics-definition-4142815
- https://www.healthline.com/health/cryotherapy-benefits#benefits
- https://www.chilledcryospa.com/what-is-cryo
- https://en.wikipedia.org/wiki/Cryosurgery
- https://en.wikipedia.org/wiki/Cryoelectronics
- https://en.wikipedia.org/wiki/Cryobiology
- National Institute of Standards and Technology
